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A reinterpretation: Evidence for the exclusion of corner brominated cyclopropane in the bromination of trans-cyclopropane-1,1,2,3-d4

✍ Scribed by Merle A. Battiste; James M. Coxon


Book ID
104219559
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
100 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis


The results of bromination of trans-cyclopropane-1,1,2,3-d4 have been reinterpreted and require an unsymmetrical reactmathway thereby excluding the formation of a corner brominated reaction intermediate.


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Acetolysis of 4-bromobutyl-1,1-d2 p-nitr
✍ Walter S. Trahanovsky; G.Leroy Smyser; Michael P. Doyle πŸ“‚ Article πŸ“… 1968 πŸ› Elsevier Science 🌐 French βš– 198 KB

We wish to report that acetolysis of 4-bromobutyl-1,1-d, p-nitrobenzenesulfonate leads to 78% of the unrearranged product, 4-bromobutyl-l,l-& acetate, and 22$ of the rearranged product, 4-bromobutyl-4,4-h acetate.