A redetermination of cis-aquabis(glycinato-κ2N,O)copper(II)
✍ Scribed by Casari, Barbara M. ;Mahmoudkhani, Amir H. ;Langer, Vratislav
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 291 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title complex, [Cu(C 4 H 6 N 2 O 3 )(C 5 H 5 N 5 )(H 2 O)], the Cu II atom is five-coordinated in a square-pyramidal geometry by a tridentate glycylglycinate ligand (glygly), an N atom from an adenine ligand (Hade) and a water molecule in the apical position. The Hade coordination is reinforc
In the title complex, [Cu(C~8~H~6~NO~2~)~2~(C~6~H~7~NO)~2~(H~2~O)], the Cu^2+^ ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment, and is bonded to three carboxylate O atoms of two 3-pyridylacrylate anions (monodentate and asymetric bidentate), two pyridine N atoms of
In the title compound, [Cu(Cl~2~CHCO~2~)~2~(C~6~H~6~N~2~O)~2~(H~2~O)], both the Cu^II^ atom and the O atom of the coordinated water molecule lie on a crystallographic twofold rotation axis. The Cu^II^ atom is coordinated by O atoms from two monodentate chloroacetate anions, pyridine N atoms from two
Single-crystal X-ray study T = 297 K Mean '(C±C) = 0.003 A Ê R factor = 0.024 wR factor = 0.068 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.032 wR factor = 0.089 Data-to-parameter ratio = 12.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.