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A Rearrangement in the λ5-Phosphorin Series Analogous to the Claisen Rearrangement

✍ Scribed by Dr. Ortwin Schaffer; Prof. Dr. Karl Dimroth

Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
253 KB
Volume
14
Category
Article
ISSN
0044-8249

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Aromatic Claisen Amino Rearrangement in the Series of Fluorinated Anilines. -The influence of the m-substituent on the acid-catalyzed Claisen rearrangement of the N-pentenylanilines (I), (IV), and (VII) is studied. The rearrangement affords a mixture of two o-pentenylanilines in ratios depending on