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A Re-examination of the Peroxyacid Cleavage of Ketones. II. Kinetics of the Baeyer-Villiger Reaction

✍ Scribed by Hawthorne, M. Frederick; Emmons, William D.


Book ID
126271801
Publisher
American Chemical Society
Year
1958
Tongue
English
Weight
841 KB
Volume
80
Category
Article
ISSN
0002-7863

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## Abstract Under __Mannich__ reaction conditions (diethylamine and formaldehyde in toluene under reflux) lasalocid (**1**) undergoes a unique transformation in which the carboxyl group is replaced by a diethylaminomethyl group. The resulting __Mannich__ base **2** was converted back to lasalocid,