A rapid method for the preparation of O2 from CO2 for mass spectrometric measurement of 17O/16O ratios

✍ Scribed by Carl A.M. Brenninkmeijer; Thomas Röckmann

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 90 KB
• Volume: 12
• Category: Article
• ISSN: 0951-4198
• DOI: 10.1002/(sici)1097-0231(19980430)12:8<479::aid-rcm184>3.0.co;2-r

✦ Synopsis

Following the discovery of strong oxygen isotope enrichment in stratospheric O 3 and in particular the puzzling concomitant large excess enrichment in 17 O, more atmospheric gases, importantly CO 2 and CO, have been found to suffer from this effect, known as mass independent fractionation. Understanding this new category of isotope effects, which for O 3 appears to be a rare, symmetry related kinetic isotope effect, is of fundamental importance. Moreover, the search for the presence of mass independent fractionation effects in atmospheric trace gases and understanding their causes is of interest to atmospheric chemistry. Conventional accurate oxygen isotope ratio analysis is based on mass spectrometry of CO 2 . However, using CO 2 does not allow measurement of the 17 O/ 16 O ratio due to isobaric interference from 13 C variations. Therefore, conversion to O 2 is necessary, for which a fast and safe method has been developed. The essence of the new method is that CO 2 is first converted to H 2 O and CH 4 by reacting it with H 2 . To increase reaction speed and to achieve quantitative conversion, a Ni powder catalyst is used at its Curie point. Subsequently, the formed H 2 O readily reacts with F 2 to form the desired O 2 with HF as waste product. A safe reaction is assured by using a mixture of only 5% F 2 in He. The validity of the produced isotope ratios is verified independently.