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A quantum mechanical study of dissociative He+H2 collisions

✍ Scribed by K. Nobusada; K. Sakimoto


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
595 KB
Volume
197
Category
Article
ISSN
0301-0104

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Results from a time-dependent quantum-mechanical study of the collinear reaction He+H: +HeH+ +H are reported in the form of reaction probability values as a function of the total energy of the system for different vibrational states of Hz. The resonances are related to flux patterns similar to that

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The previous quantum mechanical close-coupling study of the dissociative collisions in He + Hz (T-shape configuration) by the present authors [Chem. Phys. Letters 216 (1993) 6131 has been extended to a wide range of the total energy 4.8-7.5 eV. The dissociation process shows a clear vibrational enha

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The semi-classical coupled wavepacket method is used to investigate the dissociative charge exchange reaction He+ +H2( IJ= O-4 ) +He + H + H+ and the vibronic excitation reaction He+ + H2( v= O-4) +He+ + Hz (u' ) . The center of mass collision energy ranges from 2 to 10 eV. The cross sections strong