The cncrgy -rransfcr process, H&P,) f CO(O) -Hg('S~)+CO(v),hnsbccn nudisd by tie mexurcmen~oCthcLR flubrescerlce of CO. urine modulafed H&resonant radiation to excite Hg atoms. The cross section for each final vibrationallevelof v = 2 to 9 is 0.045, 0.091, 0.15, 0.17, 0.15, 0.065, 0.013, and 0.006 A
A quantum mechanical investigation of vibrational energy transfer in O(3P) + CO2 collisions
โ Scribed by Nancy Mullaney Harvey
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 431 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
Cross sechons for vibrallonal clckmon of C02(rr1rr,hnj) III colhs~ons with 0(3P) xc crlcuhtcd for rcbt~vc colbs~on energies of 1.040 eV by lhc vibrational close-couplinE rotational mfmltc order sudden method. Results UC compared with recently pubhshed quasiclassicll trajectory results
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Diffcrential cross sections of thc process Na\*(3 \*P) + M(u = 0) Na(3S) + M(u') have been mcasured for several molecules: Hz, D2, Nz, 02, CO, COz, NzO, Cz H4. WC observe two different types of enerpy spectra. One of them displays il typicalIy non-resonant elcctronic to vibrational energy transfer a
An approlimatc approach is dcvelopcd to study the interfcrcncc of one-and twoquantum processes in collinear collisions of an atom and a harmonic oscillator. !n deriving an esplicit espression for vibrational transition probabilities, oncquantum processes arc trcatcd rigorously. while the contributio
A many-body approach to motecuhr collisions is applied to the L~icuhtion of vibrational-rotational transition probtlbilities of ionsstztttered from linear triztomic molecules\_ The system Li+-CO2 has been chosen in order to comprtre the theoretical predictions with e..perimental resultr Good amment