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A Quantum-chemical study of the mechanism of formation of styrene polymerization centers under initiation by the ferrocene—benzoyl peroxide system

✍ Scribed by A. K. Frizen; S. L. Khursan; S. V. Kolesov; Yu. B. Monakov

Book ID
111472553
Publisher
Pleiades Publishing
Year
2009
Tongue
English
Weight
174 KB
Volume
3
Category
Article
ISSN
1990-7931

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✍ J. Lane; B.J. Tabner 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 408 KB

Electron spin resonance spectroscopy has been used, in conjunction with the spin-trapping technique (employing 2-methyl-2-nitrosopropane as a spin-trap), to study the benzoyl peroxide initiated homopolymerization of styrene in benzene. The initial rate at which the polystyryl spin-adduct is formed i