A quantum chemical investigation of the metal-to-ligand-charge-transfer photochemistry
β Scribed by D. Guillaumont; C. Daniel
- Book ID
- 108315078
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 361 KB
- Volume
- 177
- Category
- Article
- ISSN
- 0010-8545
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π SIMILAR VOLUMES
Metal-to-ligand charge-transfer (MLCT) excitation of organometallic and coordination complexes has diverse chemical and physical consequences, depending on the molecular structure and the medium. It can promptly start an ultrafast ligand dissociation, populate a long-lived, charge-separated, 3MLCT s
In contrast to the UV-photoinduced ligand photoionization of the flavonoid complexes of Fe III , redox reactions initiated in ligand-to-metal charge-transfer excited states were observed on irradiation of the quercetin (1) and rutin (2) complexes of Cu II . Solutions of complexes with stoichiometrie