A pulse radiolysis and flash photolysis study of the formation and characterization of platinum (III) amine complex ions
β Scribed by J.C. Brodovitch; D.K. Storer; W.L. Waltz; R.L. Eager
- Publisher
- Elsevier Science
- Year
- 1976
- Weight
- 937 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0020-7055
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The photolysis of phenylazotriphenyl methane (PAT) in dichloromethane and acetonitrile solution at and at 23Β‘C results in the j inc \ 347 nm formation of triphenyl methyl (trityl) radicals and trityl ions. The quantum yields in dichloromethane solution are and Trityl '(Ph ions are assumed to be for
In benzene solution, C60 and C7o interact weakly in the ground state with amines having favourable oxidation potentials. Picosecond time-resolved absorption measurements show that on photoexcilation, the weak complexes undergo charge separation to produce ion pairs which in turn undergo fast geminat