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A proposed mechanism for peroxidase action based on a kinetic study of luminescent and non-luminescent peroxidation reactions

✍ Scribed by Leon S. Dure; Milton J. Cormier


Book ID
118848166
Publisher
Elsevier Science
Year
1963
Tongue
English
Weight
255 KB
Volume
11
Category
Article
ISSN
0006-291X

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Part of the reaction between 2H-pyran-2-ones and organomagnesium compounds has been investigated by means of MNDO and ab initio calculations. Criteria for the mechanism of reaction are provided by the stereoselectivity observed and calculations are consistent with this stereoselectivity. Conformatio