A precise determination of the proton coupling parameters in benzene
β Scribed by J.M. Read Jr.; R.E. Mayo; J.H. Goldstein
- Book ID
- 107801247
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- English
- Weight
- 383 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0022-2852
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π SIMILAR VOLUMES
The first ionization potentials of benzene and benzeneil6 have been precisely determined by the extrapolation of three-photon resonant Rydberg states in the four-phoron ionization spectrum of the jet-cooled molecule. The convergence of resoived transitions in two Rydberg series for principal quantum
also required of the values of Jo determined from canpounds with the same substituents in & and meta positions; and of the values of J, determined from ortho. meta and E-disubstituted benzenes. This treatment of the data offers the opportunity of deducing spectral parameters of benzene as accurate
## Abstract From the single and double resonance ^1^H NMR spectra of triphenylphosphine, magnitudes and relative signs of the protonβproton and protonβphosphorus spin coupling constants were calculated. The values of these parameters were found to be nearly equal to those of the respective ^1^Hβ^1^