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A practical synthesis of chiral and achiral phosphonium salts from phosphine borane complexes

✍ Scribed by Jacques Uziel; Nadège Riegel; Benoît Aka; Pierre Figuière; Sylvain Jugé

Book ID
104257011
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
214 KB
Volume
38
Category
Article
ISSN
0040-4039

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A general synthesis of optically active
A general synthesis of optically active phosphines, phosphinites and thiophosphinites from alkylthio(alkylseleno)phosphonium salts and tris(dimethylamino)phosphine as a thiophilic agent
✍ J. Omelańczuk; M. Mikołgajczyk 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 249 KB

## Tris(dimethylaminolphosphine was found to be a suitable thiophilic reagent which converts optically active aZkyZthiofaZkyZseZeno!phosphosphonium salts into chiral tertiary phosphines and phosphinites with a high stereosetectivity. The first synthesis of opticaZZy active thiophosphinites from bi