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A practical route to enantiopure 1,2-aminoalcohols

✍ Scribed by Han-Ting Chang; K.Barry Sharpless

Book ID
103403478
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
238 KB
Volume
37
Category
Article
ISSN
0040-4039

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A General Synthesis of Enantiopure 1,2-A
A General Synthesis of Enantiopure 1,2-Aminoalcohols via Chiral Morpholinones
✍ Fabienne Segat-Dioury; Olivier Lingibé; Bernadette Graffe; Marie-Claude Sacquet; 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 304 KB

Eleven optically active 1,2-aminoalcohols 20a-i and 26b-c were prepared from d-phenylglycine via cyclic imines 7b-i (or enamine 7a). The key step of the strategy is the diastereoselective reduction of chiral oxazinones 7a-i.