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A General Synthesis of Enantiopure 1,2-Aminoalcohols via Chiral Morpholinones

✍ Scribed by Fabienne Segat-Dioury; Olivier Lingibé; Bernadette Graffe; Marie-Claude Sacquet; Gérard Lhommet

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
304 KB
Volume
56
Category
Article
ISSN
0040-4020

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✦ Synopsis

Eleven optically active 1,2-aminoalcohols 20a-i and 26b-c were prepared from d-phenylglycine via cyclic imines 7b-i (or enamine 7a). The key step of the strategy is the diastereoselective reduction of chiral oxazinones 7a-i.

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ChemInform Abstract: A General Synthesis
ChemInform Abstract: A General Synthesis of Enantiopure 1,2-Amino Alcohols via Chiral Morpholinones.
✍ Fabienne Segat-Dioury; Olivier Lingibe; Bernadette Graffe; Marie-Claude Sacquet; 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 41 KB 👁 2 views

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