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A practical preparation of ?-hydroxy and ?,?-dihydroxy aldehydes, useful intermediates for the synthesis of arachidonic acid metabolites, starting with D-glyceraldehyde acetonide

✍ Scribed by Okamoto, Sentaro; Shimazaki, Toshiyuki; Kitano, Yasunori; Kobayashi, Yuichi; Sato, Fumie

Book ID: 121307686
Publisher: The Royal Society of Chemistry
Year: 1986
Tongue: English
Weight: 268 KB
Volume: 17
Category: Article
ISSN: 0022-4936
DOI: 10.1039/C39860001352

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Chiral α-hydroxy- and α,β-dihydroxy- ald

Chiral α-hydroxy- and α,β-dihydroxy- aldehydes from D-isoascorbic and L-ascorbic acids. Useful precursors for the synthesis of fatty acid metabolites.

✍ Y Le Merrer; C Gravier-Pelletier; J Dumas; J.C Depezay 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 273 KB

&mm6fy : The four possible stereoisomers of a$dihydroxyaldehydes, useful building blocks for the synthesis of fatty acids metabolites, are synthesized via epoxy-tetrols derived from D-isoascorbic and L-ascorbic acids. The general method we develop allows the synthesis of chiral a-hydroxyaldehydes as