Porous coordination polymers (PCPs) have received considerable attention because of their diverse topologies and potential applications in storage, separation, and catalysis. [1][2][3][4][5][6] Besides porosity, stability, and pore shape and size, framework flexibility and pore-surface modifications
A Porous Coordination Polymer with Accessible Metal Sites and its Complementary Coordination Action
✍ Scribed by Hirotoshi Sakamoto; Ryotaro Matsuda; Sareeya Bureekaew; Daisuke Tanaka; Susumu Kitagawa
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 591 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0947-6539
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## Abstract **Stark vernetzt**: Ein dreikerniger Nickelcluster, der eine zentrale Hydroxygruppe enthält, dient als Baustein für ein hoch vernetztes, hoch symmetrisches Gerüst mit uninodaler neunfach verknüpfender Topologie. Die von den Clustern abgeleiteten Triakistetraeder bilden ein überkreuzende
## Abstract **Making connections**: A hydroxy‐centered trinuclear nickel cluster has been employed to construct a highly connected, highly symmetric framework with a uninodal nine‐connected topology. An array of triakis tetrahedra leads to a biporous intersecting‐channel system (see picture).magnif