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A Flexible Porous Coordination Polymer Functionalized by Unsaturated Metal Clusters

✍ Scribed by Jie-Peng Zhang; Satoshi Horike; Susumu Kitagawa


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
382 KB
Volume
46
Category
Article
ISSN
0044-8249

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A Flexible Porous Coordination Polymer F
✍ Jie-Peng Zhang; Satoshi Horike; Susumu Kitagawa πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 381 KB

Porous coordination polymers (PCPs) have received considerable attention because of their diverse topologies and potential applications in storage, separation, and catalysis. [1][2][3][4][5][6] Besides porosity, stability, and pore shape and size, framework flexibility and pore-surface modifications

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## Abstract The podand ligand tris(4‐carboxy‐2‐phenoxyethyl)amine (ptaH~3~) readily reacts with Co^II^, Mn^II^ and Ni^II^ salts at room temperature to afford porous coordination polymers, {Co(ptaH)Β·5H~2~O}__~n~__ (1), {[Mn(ptaH)(H~2~O)]Β·4H~2~O}__~n~__ (2), and {[Ni(ptaH)(4H~2~O)]Β·6H~2~O}__~n~__, (3