Low-valent second-and third-row transition metals typically form significant and robust MÀM bonds. [1, 2] Divalent Group 5 metals provide a puzzling exception. In principle, the d 3 electronic configuration makes them good candidates for the formation of triple bonds. Exceedingly short VV triple bon
✦ LIBER ✦
A Paramagnetic μ-Methylene Complex with a Short CrIIICrIII Bond
✍ Scribed by Dr. Seok Kyun Noh; Robert A. Heintz; Dr. Christoph Janiak; Dr. Shawn C. Sendlinger; Prof. Klaus H. Theopold
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- English
- Weight
- 365 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0044-8249
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## Abstract Colliding double deckers: Addition of zinc to a reaction mixture of [{Cp\*RuCl}~4~]/pentamethyl‐2,3‐dihydro‐1,3‐diborole (C~3~B~2~Me~5~H) in THF leads to three known double‐ and triple‐decker complexes of [C~3~B~2~Me~5~]^−^, and unexpectedly to the slipped triple‐decker (see picture) wi