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A Palladium-Catalyzed Tandem Cyclization-Cross-Coupling Reaction Using Indolylborate as a Transfer Agent.

✍ Scribed by Minoru Ishikura; Norinobu Takahashi; Koji Yamada; Reiko Yanada

Book ID
101999355
Publisher
John Wiley and Sons
Year
2007
Weight
31 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

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A concise access to 2-allenylindole deri
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The pailadium catalyzed cross-coupling reaction of trialkyl(indol-2-yl)borates with prop-2-ynyl carbonates was developed for the preparation of 2-allenylindole derivatives. When the reaction of indolylborates with tert-prop-2-ynyl carbonates was carried out, 2-allenylindoles were obtained solely. Ot