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A palladium catalyzed conversion of halohydrins to ketones

โœ Scribed by Jiro Tsuji; Hideo Nagashima; Koji Sato


Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
216 KB
Volume
23
Category
Article
ISSN
0040-4039

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Alkylidenecyclopropanes react with ketones under neutral conditions, in the presence of a catalytic amount of Pd(PPh 3 ) 4 to afford the corresponding a-allylated ketone products, in moderate to good yields.

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2004 Halogenation Halogenation O 0235 Conversion of Epoxides into Halohydrins with Elemental Halogen Catalyzed by Thiourea. -Thiourea is found to be an efficient catalyst for the ring opening of epoxides (I) and (IV) with iodine or bromine under mild conditions to give ฮฒ-iodoand ฮฒ-bromohydrins in go