A package compound of a metal atom with a hydrocarbon [4][4][4][4][3](1,2,3,4,5)ferrocenophane
✍ Scribed by Masao Hisatome; Yoshiki Kawajiri; Koji Yamakawa; Yoshinori Harada; Yoichi Iitaka
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 232 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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rac-E ´thyle 7-(4-chlorophe ´nyl)-3a-me ´thyl-3-(4-nitrophe ´nyl)-4a,5-diphe ´nyl-3a,4a,8,13te ´trahydro-4H-bis[1,2,4-triazolo][4,3-a:3 0 0 0 ,4 0 0 0 -d]-[1,5]benzodiaze ´pine-1-carboxylate
## Abstract A series of 3a,5‐diaryl‐1,3‐diphenyl‐3a,4,5,6‐tetrahydro‐3H‐1,2,4‐triazolo[4,3‐a][1,5]benzo‐diazepines was synthesized by the cycloaddition reactions of 2,4‐diaryl‐2,3‐dihydro‐1H‐1,5‐benzo‐diazepines and N‐phenylbenzonitrileimine generated from N‐phenylbenzenecarbohydrazonic chloride in
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.065 wR factor = 0.172 Data-to-parameter ratio = 15.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The X-ray crystallographic study of the title compound, C 24 H 20 ClN 3 OS, clearly demonstrates that 1,3-dipolar cycloaddition occurs at the C N double bond of the 1,5benzodiazepine.