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A Novel Uranyl Complex with Dimeric Lacunary Polyoxoanion: [(A-α-SiW9O33)2K{UO2(H2O)}2]11−

✍ Scribed by Ya-Guang Chen; Fan-Xia Meng; Hai-Jun Pang; Dong-Mei Shi; Yu Sun


Book ID
106406320
Publisher
Springer
Year
2006
Tongue
English
Weight
367 KB
Volume
18
Category
Article
ISSN
1040-7278

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The title compound, bis(propane-1,2-diaminium) tetraaquadi-2 -sulfato-disulfatotetraoxodiuranate(VI) dihydrate, 2+ cations balancing the charge. The dimers form hydrogen-bonded layers. The cations and occluded water molecules participate in an extensive hydrogen-bonding network. Each U VI centre is