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(C3H12N2)2[UO2(H2O)2(SO4)2]2·2H2O: an organically templated uranium sulfate with a novel dimer type

✍ Scribed by Doran, Michael B. ;Norquist, Alexander J. ;O'Hare, Dermot

Book ID: 104483873
Publisher: International Union of Crystallography
Year: 2005
Tongue: English
Weight: 291 KB
Volume: 61
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536805009682

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✦ Synopsis

The title compound, bis(propane-1,2-diaminium) tetraaquadi-2 -sulfato-disulfatotetraoxodiuranate(VI) dihydrate,

2+ cations balancing the charge. The dimers form hydrogen-bonded layers. The cations and occluded water molecules participate in an extensive hydrogen-bonding network. Each U VI centre is seven-coordinate with a pentagonal-bipyramidal geometry. Both pendent and bridging sulfate tetrahedra are observed, as well as bound and occluded water molecules.

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