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A Novel Synthetic Method for β-Keto Esters.

✍ Scribed by Hao Qian; Chunrong Ge; Xian Huang


Publisher
John Wiley and Sons
Year
2007
Weight
19 KB
Volume
38
Category
Article
ISSN
0931-7597

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## Abstract 17 monodentate phosphepine ligands with a 4,5‐dihydro‐3__H__‐dinaphtho[2,1‐__c__;1′,2′‐__e__]phosphepine structural motif have been synthesized and tested in the asymmetric hydrogenation of various β‐keto esters. By variation of the substituents of the aryl group on the phosphorus atom