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A novel synthesis of α,β-unsaturated nitriles from aromatic ketones via cyanophosphates

✍ Scribed by Shinya Harusawa; Ryuji Yoneda; Takushi Kurihara; Yasumasa Hamada; Takayuki Shioiri

Publisher: Elsevier Science
Year: 1984
Tongue: French
Weight: 134 KB
Volume: 25
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)99902-7

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✦ Synopsis

Reaction of aromatic ketones with diethyl phosphorocyanidate in the presence of lithium cyanide gave cyanophosphates, which were converted into a,@unsaturated nitriles by treatment with boron trifluoride etherate in high yields.

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