A novel stereoselective synthesis of 1,2,3-trisubstituted cyclopentanes
β Scribed by T. Akiyama; T. Fujii; H. Ishiwari; T. Imagawa; M. Kawanisi
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 123 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
The stereoselective synthesis of trisubstituted tetrahydrofurans from benzyl diazoacetate and cΒ’-alkyl-~-benzyloxyaldehydes or cΒ’-alkyl-~-(triethylsilyl)oxyaldehydes is described.
Anodic oxidative decarboxylation of endo-3-methoxycarbonyl-7-oxabicyclo[2.2.llheptane-endo-2-carboxylate anion gave exclusively an oxygenassisted Wagner-Meerwein-rearranged product, methyl 3-methoxy-2-oxabicyclo[2.2.1]heptane-anti-7-carboxylate, constituting a method for the stereospecific synthesis
## Abstract For Abstract see ChemInform Abstract in Full Text.