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A novel route to 2-fluoromethyl- and 2-hydroxymethyl-4-alkyl furans via allene oxides

✍ Scribed by Marek M. Kabat

Book ID
103404484
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
260 KB
Volume
37
Category
Article
ISSN
0040-4039

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## Abstract Swern oxidation of 2‐alkenyl‐substituted 2‐siloxy‐1‐(hydroxymethyl)cyclopropanes 7 and 11 ‐ 16 provided 2,5‐dihydrooxepines 8 and 17‐21, respectively. The corresponding cyclopropanecarboxaldehydes are highly plausible intermediates in this transformation, which give the seven‐membered h