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A novel rearrangement reaction of β-diazo-α-ketoacetals

✍ Scribed by Marvis O. Erhunmwunse; Patrick G. Steel

Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
530 KB
Volume
50
Category
Article
ISSN
0040-4039

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✦ Synopsis

Treatment of pyruvate ketal-derived diazoacetoacetates or vinyldiazoketones with rhodium(II) complexes at elevated temperatures results in an unusual skeletal rearrangement to afford eight-membered ring lactones.

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