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ChemInform Abstract: An Efficient Methodology to Substituted Furans via Oxidation of Functionalized α-Diazo-β-ketoacetates.

✍ Scribed by Phong Truong; Xinfang Xu; Michael P. Doyle

Publisher: John Wiley and Sons
Year: 2011
Weight: 40 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201132088

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✦ Synopsis

Abstract

Oxidative cyclization of α‐diazoesters of type (I) and subsequent dehydration offers an efficient access to 3‐methoxyfuran carboxylate esters (IV) and an improved method for the synthesis of 3‐hydrofuran carboxylate esters (V).

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