Aromatic isocyanates react with N-aryl phosphoramiditea to give amidino phoephonates (e.g. I) in highly exothermic reactions (1) (EtO)oP-NHPh + PhWCO -(EtO)aP-C-NRPh
A novel rearrangement of alkyl (n-alkylamido) methyl sulfides
✍ Scribed by Yasuo Kurebayashi; Yoshiharu Ishikawa; Yoshiyasu Terao; Minoru Sekiya
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 186 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract __tert__‐ Alkyl sulfides are conveniently prepared from α‐(1__H__‐benzotriazol‐1‐yl)alkyl sulfides by displacement of the 1__H__‐benzotriazol‐1‐yl group with __Grignard__ reagents. The 1‐[α‐(alkylthio)alkyl]‐ and 1‐[α‐(arylthio)alkyl]‐1__H__‐benzotriazole intermediates are easily availa
## Abstract Reaction of __N__‐benzyl‐__N__, __N__‐di‐(__p__‐nitrobenzene)sulfonamide (**3**) with NaCN/HMPA at 140° affords __N__‐benzyl‐__p__‐nitroaniline (**4**). The same product is obtained upon heating of the sodium salt of __N__‐benzyl‐(__p__‐nitrobenzene)sulfonamide (**5**). The transformati