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A Novel Rearrangement Involving Indole Dimers

โœ Scribed by NOLAND, WAYLAND E.; HAMMER, CHARLES F.

Book ID
115511269
Publisher
American Chemical Society
Year
1960
Tongue
English
Weight
968 KB
Volume
25
Category
Article
ISSN
0022-3263

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A Novel Abnormal Rearrangement in the Fischer Indole Synthesis. -Application of naltrexone (I) and the tetrahydronaphthylhydrazones (II) gives the expected indole derivatives (III) and an abnormal product (IV) probably via a [3,3] sigmatropic rearrangement. Interestingly, the hydrazone (Ia) lacking