A novel reaction of nitrosobenzene with benzylamine
β Scribed by Kazuo Suzuki; Elizabeth K. Weisburger
- Book ID
- 104236331
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- French
- Weight
- 129 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
Arylidene imines ofti-aminoesters react with nitrosobenzene at room temperature yielding a diarylnitrone and a Z-diimine.Adecuate mechanistic scheme is postulated to account for the products formed. Imines of d-aminoester
4-methoxyphenyl)-1,3,5-triazinane A 1:1 adduct produced in the reaction of nitrosobenzene (2) the NΠ-(4-methoxyphenyl)-N-phenyl-N-oxyformamidinium species 5. with 1,3,5-tris(4-methoxyphenyl)-1,3,5-triazinane (3) has been shown by X-ray diffraction structure analysis to be Recent studies [1] have g
~ ~ ~~ ~~~ ~~~- Formaldehyde reacts with substituted nitrosobenzenes giving the corresponding N-phenylhydroxamic acids. A mechanism involving three sequential steps in this reaction is proposed. The first step is the nucleophilic attack of the nitroso group on the carbonyi group which leads to the