A novel proton-transfer compound: piperazinium oxalate monohydrate
✍ Scribed by Aghabozorg, Hossein ;Ghadermazi, Mohammad ;Sheshmani, Shabnam
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 326 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The asymmetric unit of the title compound, C 4 H
ÁH 2 O, contains one water molecule, one anion and two half-cations, both cations having chair conformations. The crystal structure is stabilized by intra-and intermolecular O-HÁ Á ÁO and N-HÁ Á ÁO hydrogen bonds, linking the molecules into a three-dimensional framework, which results in the formation of a supramolecular structure based on a hydrogenbonded network.
📜 SIMILAR VOLUMES
The occurrence of the excited-state intramolecular proton transfer (ESIPT) for 1 0-hydroxybenzo [ hlquinoline is reported. The tautomer emission was observed with a maximum at 609 nm and a yield of z 2.0~ 10m2 in methylcyclohexane at room temperature. The ESIPT reaction is free from solvent perturba