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A novel porous network with interpenetrating topology

✍ Scribed by Jian Wu

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
196 KB
Volume
44
Category
Article
ISSN
0232-1300

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✦ Synopsis

Abstract

A new Co^II^ coordination polymer with complicated topology, namely [Co(bpp)~2~Cl~2~]n (1) (bpp=1,3‐bis(4‐pyridyl)propane), has been designed and synthesized based on flexible ligand under basic condition. The complex was characterized by single‐crystal X‐ray analysis and infrared spectroscopy. The Co^II^ ions are linked into a 3D structure via bpp molecules. Four independent frameworks are related by translation along the c tetragonal axis in the usual interpenetration topology for diamondoid frames. (Β© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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Figure 8 Nonlinear transmittance of the step-like structure in comparison with the linear one calculated for different values of 0 the characteristic frequency of the first and second fibers The nonlinear transmittance of a step-like structure with a linear characteristic frequency V of the first f