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A novel polymerization behavior of spiroorthoester: an equilibrium polymerization

✍ Scribed by Chikaoka, Satoyuki; Takata, Toshikazu; Endo, Takeshi


Book ID
126179857
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
182 KB
Volume
24
Category
Article
ISSN
0024-9297

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Crosslinked poly(cyclic orthoester)s prepared by radical additions of poly(cyclic orthoester)s possessing exomethylene groups and dithiols efficiently depolymerized to bifunctional spiro orthoesters in the presence of trifluoroacetic acid in dichloromethane. Furthermore, the dithiol-linked bifunctio