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A novel pathway for the synthesis of a carboxylic acid-functionalised Ru(II) terpyridine complex

✍ Scribed by Jérôme Husson; Marc Beley; Gilbert Kirsch

Book ID: 104253062
Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 230 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)00123-0

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✦ Synopsis

A new terpyridinyl ruthenium(II) complex functionalised with a carboxylic acid moiety was synthesised. This complex was prepared according to two different pathways. The first one successively involves protection of the carboxylic group on the ligand before formation of the complex followed by hydrolysis. The second one is a new route based on oxidation of a furan ring directly on the complex.

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