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A novel one-pot synthesis of β-hydroxy 1,3-dienes via allylic ylide-anion

✍ Scribed by Yanchang Shen; Tielin Wang


Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
121 KB
Volume
32
Category
Article
ISSN
0040-4039

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✦ Synopsis


SuFmary:. A novel one-pot s nthesis of B-hydroxy 1,3-dienes via allylic ylideanion with high stereoselec X. ivlty is described.


📜 SIMILAR VOLUMES


Efficient Synthesis of Trialkyl 3-Phenyl
✍ Issa Yavari; Loghman Moradi; Ako Mokhtarporyani-Sanandej; Anvar Mirzaei 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 German ⚖ 51 KB

## Abstract Alkyl 2‐nitroacetates **2** react with alkyl phenylpropiolates **1** in the presence of Ph~3~P in a mechanistically novel reaction to afford trialkyl 3‐phenylbuta‐1,3‐diene‐1,2,4‐tricarboxylates in yields of 60–80% under neutral conditions.