Treatment of allylic esters such as allyl benzoate (3a), allyl phenylacetate (4), allyl 3-phenylpropanoate (5), crotyl esters 14, 4-bromo-2-butenyl esters 15, and 1,4-bis(aroyloxy)-2-butenes 16 with NOBF4 in CH3CN at -23Β°C gave alkanoyloxy (or aroyloxy)-2-isoxazolines and 3-substituted 4-alkanoyloxy
A novel method for the facile synthesis of depsipeptides
β Scribed by Chaim Gilon; Yakir Klausner; Alfred Hassner
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 174 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
A one pot, high yield synthesis of depsipeptides is described involving room temperature condensation of hindered substrates (N-BOC amino acids and benzyl cc-hydroxy esters) in the presence of DCC and a dialkylaminopyridine. lo. 40 5. M. M.
π SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
A one-pot approach to the synthesis of novel glycosylidene-based quinolines is described. The reaction involves a Lewis acid catalyzed Povarov addition followed by oxidation of the resulting spiroanellated tetrahydroquinoline intermediates to yield the open-ring glycosylidene-derived quinoline.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
## Abstract magnified image An efficient synthesis of thiocoumestan derivatives, starting from catechols and 4βmercaptocoumarin in the presence of potassium ferricyanide as an oxidizing agent (Decker oxidation) was developed. The results indicate that the 4βmercaptocoumarin participates in Michael