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A novel, metal alkyl-free catalyst for the ring-opening polymerization of cyclo-olefins

✍ Scribed by P.R. Marshall; B.J. Ridgewell

Publisher: Elsevier Science
Year: 1969
Tongue: English
Weight: 249 KB
Volume: 5
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(69)90100-1

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✦ Synopsis

Abstraet--Cyclo-olefins may be polymerized under very mild conditions to give linear polymers using a mixture of WCI6 and A1Br3. No metal alkyls are involved. The polymers contain no vinylic unsaturation.

* Commercial product, 60 per cent trans, 30 per cent cis, I0 per cent saturated material. t This evidence does not exclude the presence of macrocylic structures. * Courtauld models.

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