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A Novel Ligand Modification and Diamond-core Molybdenum(IV) 2,6-Bis(2,2-diphenyl-2-thioethyl)pyridinate(2-) Complex

✍ Scribed by Gourlay, Craig; Doonan, Christian J.; White, Jonathan M.; Young, Charles G.


Book ID
127010116
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
332 KB
Volume
47
Category
Article
ISSN
0020-1669

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The X-Ray structures of the 1:l copper(I1) complexes with racemic and optically active (+)-(R,R)-(2,6bis(pyrro1idin-2-y1)pyridine ((+)-bpp; (+)-I) were determined. Whereas the perchlorate 1 of the racemic complex contains the monomeric units with perfect C, symmetry, the sulfate of the optically act