A Novel Host/Guest System with a Nanometer Large Cavity for Anions and Cations: [2NH, 2Cl− ⊂ V14O22(OH)4(H2O)2-(C6H5PO3)8]6−
✍ Scribed by Prof. Dr. Achim Müller; Dipl.-Chem. Kai Hovemeier; Dipl.-Chem. Ralf Rohlfing
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- English
- Weight
- 504 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0044-8249
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A novel molybdenum(V) phosphate decorated with nickel complex cations, Ni[Mo 6 O 12 (OH) bipy=2,2'-bipyridyl), has been hydrothermally synthesized and characterized by IR, TGA and single-crystal X-ray diffraction. Two {Mo 6 P 4 } clusters are linked via one Ni cation to form a Ni[Mo 6 P 4 ] 2 dimer
Red crystals of [H 3 O ´(dibenzo-18-crown-6)][Te 2 Br 9 ] (1) were isolated from a solution of TeBr 4 and dibenzo-18crown-6 in CH 3 CN containing a small amount of hydrobromic acid. The compound crystallizes in the triclinic space group P 1 with the cell dimensions a = 9.010(2), b = 13.403(3), c = 1
The blue mixed-crystal title compound Na 15 [Mo VI 126 Mo V 28 O 462 H 14 (H 2 O) 70 ] 0.5 [Mo VI 124 Mo V 28 O 457 H 14 (H 2 O) 68 ] 0.5 ´ca. 400 H 2 O º Na 15 [1 a] 0.5 [1 b] 0.5 ´ca. 400 H 2 O 1, which crystallizes in the triclinic space group P 1 (a = 30.785(2), b = 32.958(2), c = 47.318(3) A Ê