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A Novel High-Yield Synthesis of Substituted Isoindolequinones

✍ Scribed by Chakraborty, Manisha; McConville, David B.; Koser, Gerald F.; Tessier, Claire A.; Saito, Takeshi; Rinaldi, Peter L.; Youngs, Wiley J.

Book ID
126800036
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
208 KB
Volume
62
Category
Article
ISSN
0022-3263

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A new method for the synthesis of meso-substituted porphyrins is described: reaction of 5,10,15,20-tetrabromoporphine magnesium complex with aryl or heteroaryl boronic acids in the presence of Pd(PPh 3 ) 4 gave meso-substituted porphyrins in yields up to 70%.