A novel efficient and chemoselective method for the reduction of nitriles using the system silane/oxo-rhenium complexes
✍ Scribed by Ivânia Cabrita; Ana C. Fernandes
- Book ID
- 113928857
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- French
- Weight
- 193 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
This work reports a novel method for the reduction of sulfoxides with silanes catalyzed by high valent oxo-rhenium(V) and (VII) complexes. The catalytic system PhSiH 3 /ReIO 2 (PPh 3 ) 2 (1 mol %) proved to be highly efficient for the reduction of a wide range of sulfoxides in excellent yields under
In this work, we report the first practical application of high-valent oxo-complexes for the reduction of alkenes to the corresponding alkanes. The catalytic system Ph(Me) 2 SiH/ReIO 2 (PPh 3 ) 2 (5 mol %) proved to be very efficient for the reduction of mono-and disubstituted alkenes under solvent-