Highly Chemo- and Regioselective Reduction of Aromatic Nitro Compounds Using the System Silane/Oxo-Rhenium Complexes
✍ Scribed by de Noronha, Rita G.; Romão, Carlos C.; Fernandes, Ana C.
- Book ID
- 118246190
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 897 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
This work reports a novel method for the reduction of sulfoxides with silanes catalyzed by high valent oxo-rhenium(V) and (VII) complexes. The catalytic system PhSiH 3 /ReIO 2 (PPh 3 ) 2 (1 mol %) proved to be highly efficient for the reduction of a wide range of sulfoxides in excellent yields under
In this work, we report the first practical application of high-valent oxo-complexes for the reduction of alkenes to the corresponding alkanes. The catalytic system Ph(Me) 2 SiH/ReIO 2 (PPh 3 ) 2 (5 mol %) proved to be very efficient for the reduction of mono-and disubstituted alkenes under solvent-