A novel conversion reaction of 4-oxo-4H-1-benzopyran-3-carboxaldehydes to 3-substituted-5-(2-hydroxybenzoyl)-2(1H)-pyridones
β Scribed by Akira Nohara; Toshihiro Ishiguro; Yasushi Sanno
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- French
- Weight
- 148 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
It is well known
that the pyrone ring of chromones is cleaved at C-2
π SIMILAR VOLUMES
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## Abstract magnified image The title aldehyde **1** reacts smoothly with the enamine moiety of **2**βaminochromone **2** to produce hitherto unreported 3β(2βhydroxybenzoyl)β5__H__β1βbenzopyrano[2,3β__b__]pyridinβ5βone (azaxanthone) **5**. This reaction has been extended for the synthesis of bisaz
The chromone fmfn s 1 and benzonitrile oxide reacted regioapaciffcally to yield 6 1 -172,4 oxadiarolinyl chromonea 2\_in good yields. Also the preparation of a novel dipole & derived from f-formylchromons and its cycloaddition reactions with a variety of alkenes which gave pyrazolinyl chromones zia
## Abstract For Abstract see ChemInform Abstract in Full Text.