A novel ATRP initiating system Fe(dtc)3/FeCl3/PPh3 for MMA polymerization
โ Scribed by Chen, Xiao-Ping; Qiu, Kun-Yuan
- Book ID
- 123613653
- Publisher
- Royal Society of Chemistry
- Year
- 2000
- Tongue
- English
- Weight
- 414 KB
- Volume
- 15
- Category
- Article
- ISSN
- 1359-7345
- DOI
- 10.1039/B004471G
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๐ SIMILAR VOLUMES
The living/controlled radical polymerization of styrene was investigated with a new initiating system, DCDPS/FeCl 3 /PPh 3 , in which diethyl 2,3-dicyano-2,3diphenylsuccinate (DCDPS) was a hexa-substituted ethane thermal iniferter. The polymerization mechanism belonged to a reverse atom transfer rad
Well-deยฎned polystyrenes with an a-C(CH 3 ) 2 (CN) and an v-chlorine atom end-groups, and narrow polydispersity (M n = 3000ยฑ4000 g mol ร1 , M w /M n = 1.3ยฑ1.4) have been synthesized by a radical polymerization process using 2,2'-azobisisobutyronitrile(AIBN)/FeCl 3 /PPh 3 initiation system. When the