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A novel approach to oligocyclopropane structural units

✍ Scribed by Richard E. Taylor; Michael K. Ameriks; Matthew J. LaMarche

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
226 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

A fundamentally novel approach to the synthesis of oligocyclopropane structural units based on the iterative formation and trapping of homo-allyl cationic intermediates has been accomplished. This methodology provides practical access to the diastereomieally related trans-syn-trans and trans-ant/-trans bis-cyclopropanes and higher homologues.

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