𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A novel and general route to diverse A-ring aromatic trichothecanes via cyclobutanes

✍ Scribed by Hideo Nemoto; Junji Miyata; Keiichiro Fukumoto


Book ID
107857908
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
723 KB
Volume
52
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Total synthesis of (Β±)-4-deoxyverrucarol
✍ Hideo Nemoto; Junji Miyata; Masataka Ihara πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 194 KB

Total synthesis of 4-deoxyverrucarol (4), a trichothecane-type sesquiterpene was achieved via two types of ring expansion reaction, 1,2-rearrangement of 18 and palladium mediated ring expansion reaction of 20, as key steps providing a new route to trichothecanes.

Base-induced ring closure of bis-dithioa
✍ Theodore Cohen; Daniel Ouellette; Wlodzimlerz M. Daniewski πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 231 KB

A recent report from this laboratory disclosed an extremely efficient preparation of cyclopropanone dithioketals by treatment of dithioacetals containing a 3-phenylthio substituent with methyllithium in tetrahydrofuran (THF) containing tetramethylethylenediamine (TMEDA) at O'C. 1 We now report that