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A novel and expeditious approach to the stereoselective synthesis of 2-S-ethyl(phenyl)-2-deoxy-β-glycosides, ready precursors to 2-deoxy-β-glycosides

✍ Scribed by Biao Yu; Zunyi Yang

Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 126 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)00281-1

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✦ Synopsis

1,2-Migration and concurrent glycosidation of ethyl(phenyl) 2,3-orthoester-1-thio-α-L-rhamnopyranosides under the action of TMSOTf readily afforded the corresponding 2-S-ethyl(phenyl)-2-deoxy-β-glycosides, ready precursors to 2-deoxy-β-glycosides.

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